Electrocatalytic process in the reduction of {Nb[η5-C5H4(SiMe3)]2(Cl)(NHPh)}BF4

被引：0

作者：

Tehrani, ZM

Lucas, D

Mugnier, Y

Antinolo, A

Otero, A

Fajardo, M

Garces, A

Lopez-Mardomingo, C

机构：

[1] CNRS, UMR 5632, Fac Sci, Lab Synth & Electrosynth Organometall, F-21000 Dijon, France

[2] Univ Castilla La Mancha, Dept Quim Inorgan, E-13071 Ciudad Real, Spain

[3] Univ Alcala de Henares, Dept Quim Inorgan & Quim Organ, Alcala De Henares 28871, Spain

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 548卷 / 02期

关键词：

niobium; protonation; imido and amido complex; electroreduction;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Protonation of the biscyclopentadienyl imido niobium complex (eta(5)-C5H4SiMe3)(2)Nb(Cl)(=NPh) affords the corresponding cationic amido complex [(eta(5)-C5H4SiMe3)(2)Nb(Cl)(NHPh)](+), 1. Starting from 1, an interesting amido group elimination reaction has been found to take place, reaction which must be electrochemically induced. (C) 1997 Elsevier Science S.A.

引用

页码：309 / 313

页数：5

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