Electrocatalytic process in the reduction of {Nb[η5-C5H4(SiMe3)]2(Cl)(NHPh)}BF4

被引：0

作者：

Tehrani, ZM

Lucas, D

Mugnier, Y

Antinolo, A

Otero, A

Fajardo, M

Garces, A

Lopez-Mardomingo, C

机构：

[1] CNRS, UMR 5632, Fac Sci, Lab Synth & Electrosynth Organometall, F-21000 Dijon, France

[2] Univ Castilla La Mancha, Dept Quim Inorgan, E-13071 Ciudad Real, Spain

[3] Univ Alcala de Henares, Dept Quim Inorgan & Quim Organ, Alcala De Henares 28871, Spain

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 548卷 / 02期

关键词：

niobium; protonation; imido and amido complex; electroreduction;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Protonation of the biscyclopentadienyl imido niobium complex (eta(5)-C5H4SiMe3)(2)Nb(Cl)(=NPh) affords the corresponding cationic amido complex [(eta(5)-C5H4SiMe3)(2)Nb(Cl)(NHPh)](+), 1. Starting from 1, an interesting amido group elimination reaction has been found to take place, reaction which must be electrochemically induced. (C) 1997 Elsevier Science S.A.

引用

页码：309 / 313

页数：5

共 50 条

[21] Synthesis and structures of [Yb{η5-(C5H4)B(NiPr2)NHtBu}2{N(SiMe3)2}] and [Zr{η5-(C9H6)B(N(SiMe3)2)(C9H7)}Cl2]
Braunschweig, H
Kraft, M
Homberger, M
Breitling, FM
White, AJP
Englert, U
Williams, DJ
APPLIED ORGANOMETALLIC CHEMISTRY, 2003, 17 (6-7) : 421 - 428
[22] Reactions of the alkyltrihydroaluminate [Li(thf)2{AlH3[C(SiMe3)3]}]2.: Crystal structures of [Li(tmen)2][AlH3{C(SiMe3)3}], [AlBr2-{C(SiMe3)3}]•thf, [AlI2{C(SiMe3)3}]•thf, [Li(thf)2(μ-NHPh)2-{AlH[C(SiMe3)3]}] and {Li(thf)4][Al(NHPh)3{C(SiMe3)3}]
Al-Juaid, SS
Eaborn, C
Gorrell, IB
Hawkes, SA
Hitchcock, PB
Smith, JD
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (14): : 2411 - 2415
[23] Dicyclopentadienyl complexes of samarium(III):: [Sm(η5)-C5H4SiMe3)2(μ-Cl)]2
Spirlet, MR
Goffart, J
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 : 1624 - 1626
[24] Reaction chemistry of alkynyl-functionalized titanocenes. X-ray structure analyses of (eta(5)-C(5)H(4)SiMe(3))(2)Ti(Cl)(CH(2)SiMe(3)) and [(eta(5)-C(5)H(4)SiMe(3))(2)Ti(Cl)(C CSiMe(3))]CuBr
Lang, H
Frosch, W
Wu, IY
Blau, S
Nuber, B
INORGANIC CHEMISTRY, 1996, 35 (21) : 6266 - 6272
[25] SYNTHESIS OF MONOMERIC PERMETHYLYTTROCENE DERIVATIVES - THE CRYSTAL-STRUCTURES OF ETA-5-C5H5YN(SIME3)2 AND ETA-5-C5H5YCH(SIME3)2
DENHAAN, KH
DEBOER, JL
TEUBEN, JH
SPEK, AL
KOJICPRODIC, B
HAYS, GR
HUIS, R
ORGANOMETALLICS, 1986, 5 (08) : 1726 - 1733
[26] Synthesis and structural characterisation of [{Sn(η-Cps)}{(BF4)}] {Cps = C5Me4(SiMe2But)}
de Lima, GM
Duncalf, DJ
Constantine, SP
MAIN GROUP METAL CHEMISTRY, 2001, 24 (10): : 675 - 679
[27] Remarkable organophosphorus cage compounds from the reaction of cobaltocene and the triphosphole P3C2But2CH(SiMe3)2:: crystal and molecular structures of [Co(η5-C5H5)(η4-C4H4CHCHP6C4But4)] and P6C4But4CH(SiMe3) (pg 2720, 2001)
Hitchcock, PB
Nixon, JF
Büyükkidan, NS
CHEMICAL COMMUNICATIONS, 2002, (19) : 2278 - 2278
[28] Ferrocenylene- and Carbosiloxane-Bridged Bis(sila[1]ferrocenophanes) E[SiMe2-X-SiMeFC]2 {E = (η5-C5H4)Fe(η5-C5H4) or O; X = (CH2)n (n=2, 3, 6); CH=CH; FC = (η5-C5H4)2Fe}
Kumar, Mukesh
Metta-Magana, Alejandro J.
Pannell, Keith H.
ORGANOMETALLICS, 2008, 27 (24) : 6457 - 6463
[29] Synthesis and structures of alkali metal amides derived from the ligands [N(SiMe2Ph)(SiMe3)]-, [N(tBu)(SiMe3)]-, [N(Ph)(2-C5H4N)]- and [N(2-C5H4N)2]-
Antolini, F
Hitchcock, PB
Khvostov, AV
Lappert, MF
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2003, (18) : 3391 - 3400
[30] New silyl-substituted cyclopentadienyl titanium and zirconium complexes. X-ray molecular structures of [TiCl2{μ-(OSiMe2-η5-C5H4)}$ RB2 and [ZrCl2{μ-[(η5-C5H4)SiMe2OSiM e2 (η5-C5H4)]}]
Ciruelos, S.
Cuenca, T.
Gomez-Sal, P.
Manzanero, A.
Royo, P.
Organometallics, 1995, 14 (01):

← 1 2 3 4 5 →