Synthesis and structures of compounds of Groups 11 and 12 containing the ligand C(SiMe3)2(SiMe2C5H4N-2)

被引：22
|
作者：
Eaborn, C [1 ]
Hill, MS [1 ]
Hitchcock, PB [1 ]
Smith, JD [1 ]
机构：
[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 12期
关键词：
D O I：
10.1039/b200473a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The compound Li(thf)C(SiMe3)(2)(SiMe2C5H4N-2) (1) reacts with CuI or AuCl.SMe2 to give the dimeric compounds [MC(SiMe3)(2)(SiMe2C5H4N-2)](2) (M = Cu or Au), in which the bidentate ligand bridges two metal centres. Reactions of 1 with Group 12 halides of the form MX2 give the compounds MX{C(SiMe3)(2)(SiMe2C5H4N-(2))} (M = Zn, X = Br; M = Cd, X = Cl; M = Hg, X = Cl). In the solid state, the zinc and cadmium compounds are halogen-bridged dimers, but the mercury compound is monomeric, with only weak interaction between mercury and nitrogen.
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页码：2467 / 2472
页数：6
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