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Highly Enantioselective Recognition of Structurally Diverse α-Hydroxycarboxylic Acids using a Fluorescent Sensor
被引:113
|作者:
Liu, Hai-Lin
[1
]
Peng, Qian
[2
]
Wu, Yun-Dong
[2
,4
]
Chen, Di
[1
]
Hou, Xue-Long
[1
,2
]
Sabat, Michal
[3
]
Pu, Lin
[3
]
机构:
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai Hong Kong Joint Lab Chem Synth, Shanghai 200032, Peoples R China
[3] Univ Virginia, Dept Chem, Charlottesville, VA 22904 USA
[4] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
基金:
美国国家科学基金会;
中国国家自然科学基金;
关键词:
amino alcohols;
enantioselectivity;
fluorescence;
alpha-hydroxycarboxylic acids;
sensors;
INDICATOR-DISPLACEMENT ASSAYS;
ENANTIOMERIC EXCESS;
CATALYSTS;
MACROCYCLE;
MOLECULES;
DESIGN;
D O I:
10.1002/anie.200904889
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
(Figure Presented) The shining: Readily accessible BINOL amino alcohol (S)-I is a highly enantioselective fluorescent sensor for structurally diverse α-hydroxycarboxylic acids, and is the first highly enantioselective fluorescent sensor for the recognition of linear aliphatic α- hydroxycarboxylic acids and α-tertiary-hydroxycarboxylic acids. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
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页码:602 / 606
页数:5
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