Highly Enantioselective Recognition of Structurally Diverse α-Hydroxycarboxylic Acids using a Fluorescent Sensor

被引：113

作者：

Liu, Hai-Lin ^{[1
]}

Peng, Qian ^{[2
]}

Wu, Yun-Dong ^{[2
,4
]}

Chen, Di ^{[1
]}

Hou, Xue-Long ^{[1
,2
]}

Sabat, Michal ^{[3
]}

Pu, Lin ^{[3
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai Hong Kong Joint Lab Chem Synth, Shanghai 200032, Peoples R China

[3] Univ Virginia, Dept Chem, Charlottesville, VA 22904 USA

[4] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 03期

基金：

美国国家科学基金会; 中国国家自然科学基金;

关键词：

amino alcohols; enantioselectivity; fluorescence; alpha-hydroxycarboxylic acids; sensors; INDICATOR-DISPLACEMENT ASSAYS; ENANTIOMERIC EXCESS; CATALYSTS; MACROCYCLE; MOLECULES; DESIGN;

D O I：

10.1002/anie.200904889

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) The shining: Readily accessible BINOL amino alcohol (S)-I is a highly enantioselective fluorescent sensor for structurally diverse α-hydroxycarboxylic acids, and is the first highly enantioselective fluorescent sensor for the recognition of linear aliphatic α- hydroxycarboxylic acids and α-tertiary-hydroxycarboxylic acids. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：602 / 606

页数：5

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