Highly Enantioselective Recognition of Structurally Diverse α-Hydroxycarboxylic Acids using a Fluorescent Sensor

被引：113
|
作者：
Liu, Hai-Lin [1 ]
Peng, Qian [2 ]
Wu, Yun-Dong [2 ,4 ]
Chen, Di [1 ]
Hou, Xue-Long [1 ,2 ]
Sabat, Michal [3 ]
Pu, Lin [3 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai Hong Kong Joint Lab Chem Synth, Shanghai 200032, Peoples R China
[3] Univ Virginia, Dept Chem, Charlottesville, VA 22904 USA
[4] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 03期
基金：
美国国家科学基金会; 中国国家自然科学基金;
关键词：
amino alcohols; enantioselectivity; fluorescence; alpha-hydroxycarboxylic acids; sensors; INDICATOR-DISPLACEMENT ASSAYS; ENANTIOMERIC EXCESS; CATALYSTS; MACROCYCLE; MOLECULES; DESIGN;
D O I：
10.1002/anie.200904889
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Figure Presented) The shining: Readily accessible BINOL amino alcohol (S)-I is a highly enantioselective fluorescent sensor for structurally diverse α-hydroxycarboxylic acids, and is the first highly enantioselective fluorescent sensor for the recognition of linear aliphatic α- hydroxycarboxylic acids and α-tertiary-hydroxycarboxylic acids. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：602 / 606
页数：5
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