Bisbinaphthyl macrocycle-based highly enantioselective fluorescent sensors for α-hydroxycarboxylic acids

被引：101
|
作者：
Lin, J [1 ]
Zhang, HC [1 ]
Pu, L [1 ]
机构：
[1] Univ Virginia, Dept Chem, Charlottesville, VA 22904 USA
来源：
ORGANIC LETTERS | 2002年 / 4卷 / 19期
关键词：
D O I：
10.1021/ol026565c
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Bisbinaphthyl-based macrocycles are found to carry out highly enantioselective flourescent recogniton of alpha-hydroxycarboxylic acids. It is observed that within a certain concentration range, one enantiomer of the chiral acids can increase the fluorescence intensity of the macrocycles by 2-3-fold, while the other enantiomer scarcely enhances the fluorescence. Such unusually high enantioselective responses make these macrocycles very attractive as fluorescent sensors in determining the enantiomeric composition of alpha-hydroxycarboxylic acids.
引用
收藏
页码：3297 / 3300
页数：4
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