Bisbinaphthyl macrocycle-based highly enantioselective fluorescent sensors for α-hydroxycarboxylic acids

被引：101

作者：

Lin, J ^{[1
]}

Zhang, HC ^{[1
]}

Pu, L ^{[1
]}

机构：

[1] Univ Virginia, Dept Chem, Charlottesville, VA 22904 USA

来源：

ORGANIC LETTERS | 2002年 / 4卷 / 19期

关键词：

D O I：

10.1021/ol026565c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bisbinaphthyl-based macrocycles are found to carry out highly enantioselective flourescent recogniton of alpha-hydroxycarboxylic acids. It is observed that within a certain concentration range, one enantiomer of the chiral acids can increase the fluorescence intensity of the macrocycles by 2-3-fold, while the other enantiomer scarcely enhances the fluorescence. Such unusually high enantioselective responses make these macrocycles very attractive as fluorescent sensors in determining the enantiomeric composition of alpha-hydroxycarboxylic acids.

引用

页码：3297 / 3300

页数：4

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