The Application of Dioxygenase-Based Chemoenzymatic Processes to the Total Synthesis of Natural Products

被引：19

作者：

Lan, Ping ^{[1
]}

Ye, Sebastian ^{[2
]}

Banwell, Martin G. ^{[1
,2
]}

机构：

[1] Jinan Univ, Inst Adv & Appl Chem Synth, Guangzhou 510632, Guangdong, Peoples R China

[2] Australian Natl Univ, Inst Adv Studies, Res Sch Chem, Canberra, ACT 2601, Australia

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2019年 / 14卷 / 22期

基金：

澳大利亚研究理事会;

关键词：

chemoenzymatic; cis-1; 2-dihydrocatechols; cross-couplings; Diels-Alder cycloadditions; photochemical rearrangements; sesquiterpenes; HIGHLY OXYGENATED TROPONOIDS; TAXANE DITERPENE SYNTHESIS; ACID VITAMIN-C; MICROBIAL OXIDATION; ENANTIOSELECTIVE SYNTHESIS; ENANTIODIVERGENT SYNTHESIS; ABSOLUTE-CONFIGURATION; ENANTIOMERICALLY PURE; BIOLOGICAL EVALUATION; CIS-DIHYDROCATECHOLS;

D O I：

10.1002/asia.201900988

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This Minireview describes the exploitation of certain enzymatically derived, readily accessible, and enantiomerically pure cis-1,2-dihydrocatechols as starting materials in the chemical synthesis of a range of biologically active natural products, most notably sesquiterpenoids and alkaloids.

引用

页码：4001 / 4012

页数：12

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