Hybrid Photo-induced Copolymerization of Ring-Strained and Vinyl Monomers Utilizing Metal-Free Ring-Opening Metathesis Polymerization Conditions

被引：28
|
作者：
Krappitz, Tim [1 ]
Jovic, Kristina [1 ]
Feist, Florian [1 ,2 ]
Frisch, Hendrik [1 ]
Rigoglioso, Vincent P. [4 ]
Blinco, James P. [1 ]
Boydston, Andrew J. [4 ]
Barner-Kowollik, Christopher [1 ,3 ]
机构：
[1] QUT, Sch Chem Phys & Mech Engn, 2 George St, Brisbane, Qld 4000, Australia
[2] Max Planck Inst Polymer Res, Ackermannweg 10, D-55128 Mainz, Germany
[3] KIT, Inst Tech Chem & Polymerchem, Macromol Architectures, Engesserstr 18, D-76131 Karlsruhe, Germany
[4] Univ Wisconsin Madison, Dept Chem, 1101 Univ Ave, Madison, WI 53706 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2019年 / 141卷 / 42期
基金：
澳大利亚研究理事会;
关键词：
LIVING ANIONIC-POLYMERIZATION; ABA TRIBLOCK COPOLYMERS; COMPLEXES BEARING; MASS-SPECTROMETRY; BLOCK-COPOLYMERS; TANDEM ROMP; RAFT;
D O I：
10.1021/jacs.9b09025
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We introduce the hybrid copolymerization of two disparate monomer classes (vinyl monomers and ring-strained cyclic olefins) via living photopolymerization. The living character of the polymerization technique (metal-free photo-ROMP) is demonstrated by consecutive chain-extensions. Further, we propose a mechanism for the copolymerization and analyze the copolymer structure in detail by high-resolution mass spectrometry.
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页码：16605 / 16609
页数：5
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