Photo-induced cationic ring-opening polymerization of 4-methylene-2-styryl-1,3-dioxolane by benzylsulfonium salt

被引:0
|
作者
Park, J [1 ]
机构
[1] Sangju Natl Univ, Dept Chem Engn, Kyungbuk 386, South Korea
来源
KOREA POLYMER JOURNAL | 2001年 / 9卷 / 04期
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中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
One of the approaches to obtain functional polymer is polymerization of a monomer having two functional groups. Although polymerization of a monomer having two different types of functional group is general, the author has been interested in the polymerization of a monomer having two similar types of functional group. This work shows the preparation and selective polymerization of 4-methylene-2-styryl-1,3-dioxolane having two similar reactive double bonds via cationic polymerization at ambient temperature. Cationic ring-opening polymerization of 4-methylene-2-styryl-1,3-dioxolane using benzylsulfonium salt as a photo-initiator quantitatively afforded high molecular weight of poly (keto-ether).
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页码:206 / 209
页数:4
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