Hybrid Photo-induced Copolymerization of Ring-Strained and Vinyl Monomers Utilizing Metal-Free Ring-Opening Metathesis Polymerization Conditions

被引：28

作者：

Krappitz, Tim ^{[1
]}

Jovic, Kristina ^{[1
]}

Feist, Florian ^{[1
,2
]}

Frisch, Hendrik ^{[1
]}

Rigoglioso, Vincent P. ^{[4
]}

Blinco, James P. ^{[1
]}

Boydston, Andrew J. ^{[4
]}

Barner-Kowollik, Christopher ^{[1
,3
]}

机构：

[1] QUT, Sch Chem Phys & Mech Engn, 2 George St, Brisbane, Qld 4000, Australia

[2] Max Planck Inst Polymer Res, Ackermannweg 10, D-55128 Mainz, Germany

[3] KIT, Inst Tech Chem & Polymerchem, Macromol Architectures, Engesserstr 18, D-76131 Karlsruhe, Germany

[4] Univ Wisconsin Madison, Dept Chem, 1101 Univ Ave, Madison, WI 53706 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2019年 / 141卷 / 42期

基金：

澳大利亚研究理事会;

关键词：

LIVING ANIONIC-POLYMERIZATION; ABA TRIBLOCK COPOLYMERS; COMPLEXES BEARING; MASS-SPECTROMETRY; BLOCK-COPOLYMERS; TANDEM ROMP; RAFT;

D O I：

10.1021/jacs.9b09025

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We introduce the hybrid copolymerization of two disparate monomer classes (vinyl monomers and ring-strained cyclic olefins) via living photopolymerization. The living character of the polymerization technique (metal-free photo-ROMP) is demonstrated by consecutive chain-extensions. Further, we propose a mechanism for the copolymerization and analyze the copolymer structure in detail by high-resolution mass spectrometry.

引用

下载

页码：16605 / 16609

页数：5

共 50 条

[21] Metal-free ring-opening polymerization of glycidyl phenyl ether by tetrabutylammonium fluoride
Morinaga, Hisatoyo
Ochiai, Bungo
Endo, Takeshi
MACROMOLECULES, 2007, 40 (16) : 6014 - 6016
[22] Implementation of metal-free ring-opening polymerization in the preparation of aliphatic polycarbonate materials
Mespouille, Laetitia
Coulembier, Olivier
Kawalec, Michal
Dove, Andrew P.
Dubois, Philippe
PROGRESS IN POLYMER SCIENCE, 2014, 39 (06) : 1144 - 1164
[23] Metal-free initiator/catalyst systems for the ring opening polymerization of cyclic ester monomers
Liu Jiyan
Zhang Liming
PROGRESS IN CHEMISTRY, 2007, 19 (2-3) : 350 - 355
[24] Progress in metal-free cooperative catalysis for the ring-opening copolymerization of cyclic anhydrides and epoxides
Pappuru, Sreenath
Chakraborty, Debashis
EUROPEAN POLYMER JOURNAL, 2019, 121
[25] A recyclable metal-free catalytic system for the cationic ring-opening polymerization of glycidol under ambient conditions
Kim, Si Eun
Yang, Hyun Ji
Choi, Soonyoung
Hwang, Eunbyul
Kim, Minseong
Paik, Hyun-Jong
Jeong, Ji-Eun
Park, Young Il
Kim, Jin Chul
Kim, Byeong-Su
Lee, Sang-Ho
GREEN CHEMISTRY, 2022, 24 (01) : 251 - 258
[26] Hybrid dual cross-linked polymer networks via sequential ring-opening metathesis polymerization and thermal ring-opening polymerization of norbornyl-functionalized benzoxazine monomers
Narayanan, Jananee
Patton, Derek L.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 246
[27] Toward engineering macromolecular architectures of polymers through photoredox-mediated metal-free ring-opening metathesis polymerization
Lu, Pengtao
Boydston, Andrew
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
[28] Predicting Monomers for Use in Aqueous Ring-Opening Metathesis Polymerization-Induced Self-Assembly
Varlas, Spyridon
Foster, Jeffrey C.
Arkinstall, Lucy A.
Jones, Joseph R.
Keogh, Robert
Mathers, Robert T.
O'Reilly, Rachel K.
ACS MACRO LETTERS, 2019, 8 (04) : 466 - 472
[29] Alkyl borane-mediated metal-free ring-opening (co)polymerizations of oxygenated monomers
Zhang, Chengjian
Geng, Xiaowei
Zhang, Xinghong
Gnanou, Yves
Feng, Xiaoshuang
PROGRESS IN POLYMER SCIENCE, 2023, 136
[30] Non-metal with metal behavior: metal-free coordination-insertion ring-opening polymerization
Wang, Xin
Xu, Jiaxi
Li, Zhenjiang
Liu, Jingjing
Sun, Jie
Hadjichristidis, Nikos
Guo, Kai
CHEMICAL SCIENCE, 2021, 12 (32) : 10732 - 10741

← 1 2 3 4 5 →