New organic metals: BEDO-TTF bromomercurates

被引：12

作者：

Zhilyaeva, EI ^{[1
]}

Lyubovskaya, RN ^{[1
]}

Konovalikhin, SV ^{[1
]}

Dyachenko, ON ^{[1
]}

Lyubovskii, RB ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Chem Phys, Chernogolovka 142432, MD, Russia

来源：

SYNTHETIC METALS | 1998年 / 94卷 / 01期

关键词：

bis(ethylenedioxy)tetrathiafulvalene; electrocrystallization; bromomercurate anions; organic metals; crystal structures;

D O I：

10.1016/S0379-6779(97)04136-2

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Electrochemical oxidation of BEDO-TTF (bis(ethylenedioxy)tetrathiafulvalene) in the: presence of Bu4NHgBr3 or Bu4NHgBr3 + Bu4NBr as a supporting electrolyte in 1,2-dichloroethane (DCE) allows the isolation of (BEDO-TTF)(2)HgBr3, (BEDO-TTF)(5)Hg1.9Br6.8, (BEDO-TTF)(9)(HgBr4)(2) . 5DCE or (BEDO-TTF)Cl-0.5 . 1.5H(2)O radical cation salts depending on conditions of electrochemical synthesis. Conditions for the synthesis, crystal structures and conductivity of the resulting BEDO-TTF bromomercurates are discussed. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：35 / 40

页数：6

共 50 条

[31] New organic metal (BEDO-TTF)4Pt(CN)4&middotH2O
RAS, Moscow, Russia
Synth Met, 1 (91-93):
[32] Photostimulated optical SHG in BEDO-TTF polyiodide/polycarbonate composites
Kityk, IV
Ulanski J
Jeszka, JK
Tracz, A
ADVANCED MATERIALS FOR OPTICS AND ELECTRONICS, 1996, 6 (5-6): : 358 - 362
[33] Determination of the charge on BEDO-TTF in its complexes by Raman spectroscopy
Drozdova, O
Yamochi, H
Yakushi, K
Uruichi, M
Horiuchi, S
Saito, G
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (18) : 4436 - 4442
[34] BEDT-TTF, BEDO-TTF, and BEDSe-TTF salts with metal containing anions
Lyubovskaya, RN
Zhilyaeva, EI
Torunova, SA
Bogdanova, OA
Konovalikhin, SV
Dyachenko, OA
Lyubovskii, RB
SYNTHETIC METALS, 1997, 85 (1-3) : 1581 - 1582
[35] POLARIZABILITIES OF THE INTERMOLECULAR CONTACTS IN BEDT-TTF AND BEDO-TTF MOLECULAR-CRYSTALS
HELBERG, HW
LENZ, HC
SYNTHETIC METALS, 1993, 56 (01) : 2431 - 2436
[36] New organic metal (BEDO-TTF)(4)Pt(CN)(4)center dot H2O
Zhilyaeva, EI
Lyubovskaya, RN
Torunova, SA
Konovalikhin, SV
Dyachenko, OA
Lyubovskii, RB
SYNTHETIC METALS, 1996, 80 (01) : 91 - 93
[37] Highly-oriented BEDO-TTF molecules in metallic polymer composites
Horiuchi, S
Yamochi, H
Saito, G
Jeszka, JK
Tracz, A
Sroczynska, A
Ulanski, J
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1997, 296 : 365 - 382
[38] THE CATION RADICAL SALTS OF THE OXYGEN-SUBSTITUTED DONOR, BEDO-TTF
YAMOCHI, H
NAKAMURA, T
SAITO, G
KIKUCHI, T
SATO, S
NOZAWA, K
KINOSHITA, M
SUGANO, T
WUDL, F
SYNTHETIC METALS, 1991, 42 (1-2) : 1741 - 1744
[39] Conducting properties of Langmuir-Blodgett films based on BEDO-TTF
Vignau, L
Ohnuki, H
Ishizaki, Y
Kato, R
Imakubo, T
Izumi, M
SYNTHETIC METALS, 1999, 102 (1-3) : 1723 - 1724
[40] FERMI-SURFACE IN THE ORGANIC SUPERCONDUCTOR (BEDO-TTF)2REO4.H2O
KOVALEV, AE
PESOTSKII, SI
GILEVSKII, A
KUSHCH, ND
JETP LETTERS, 1994, 59 (08) : 560 - 564

← 1 2 3 4 5 →