New organic metals: BEDO-TTF bromomercurates

被引：12
|
作者：
Zhilyaeva, EI [1 ]
Lyubovskaya, RN [1 ]
Konovalikhin, SV [1 ]
Dyachenko, ON [1 ]
Lyubovskii, RB [1 ]
机构：
[1] Russian Acad Sci, Inst Chem Phys, Chernogolovka 142432, MD, Russia
来源：
SYNTHETIC METALS | 1998年 / 94卷 / 01期
关键词：
bis(ethylenedioxy)tetrathiafulvalene; electrocrystallization; bromomercurate anions; organic metals; crystal structures;
D O I：
10.1016/S0379-6779(97)04136-2
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Electrochemical oxidation of BEDO-TTF (bis(ethylenedioxy)tetrathiafulvalene) in the: presence of Bu4NHgBr3 or Bu4NHgBr3 + Bu4NBr as a supporting electrolyte in 1,2-dichloroethane (DCE) allows the isolation of (BEDO-TTF)(2)HgBr3, (BEDO-TTF)(5)Hg1.9Br6.8, (BEDO-TTF)(9)(HgBr4)(2) . 5DCE or (BEDO-TTF)Cl-0.5 . 1.5H(2)O radical cation salts depending on conditions of electrochemical synthesis. Conditions for the synthesis, crystal structures and conductivity of the resulting BEDO-TTF bromomercurates are discussed. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：35 / 40
页数：6
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