Carbon tetrachloride dissociatively adsorbs on the Ga-rich (4x2) reconstruction of GaAs (001) at 200 degrees C. Upon heating to 440 degrees C, the chlorine desorbs as GaCl, which etches the surface. Scanning tunneling micrographs reveal that this reaction transforms the (4x2) into a Ga-rich (3x2) structure that is interlaced with As-rich (2x4) phases. The (3x2) is well ordered, while the (2x4) phases exhibit a high degree of disorder. This work establishes the surface reaction pathway for carbon doping of GaAs with CCl4. (C) 1998 American Institute of Physics.
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Novosibirsk State Univ, Novosibirsk 630090, Russia
RAS, Inst Semicond Phys SB, Novosibirsk, RussiaNovosibirsk State Univ, Novosibirsk 630090, Russia
Lyamkina, Anna A.
Dmitriev, Dmitriy V.
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RAS, Inst Semicond Phys SB, Novosibirsk, RussiaNovosibirsk State Univ, Novosibirsk 630090, Russia
Dmitriev, Dmitriy V.
Moshchenko, Sergey P.
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RAS, Inst Semicond Phys SB, Novosibirsk, RussiaNovosibirsk State Univ, Novosibirsk 630090, Russia
Moshchenko, Sergey P.
Galitsyn, Yuri G.
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RAS, Inst Semicond Phys SB, Novosibirsk, RussiaNovosibirsk State Univ, Novosibirsk 630090, Russia
Galitsyn, Yuri G.
Toropov, Alexander I.
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RAS, Inst Semicond Phys SB, Novosibirsk, RussiaNovosibirsk State Univ, Novosibirsk 630090, Russia
Toropov, Alexander I.
2009 INTERNATIONAL SCHOOL AND SEMINAR ON MODERN PROBLEMS OF NANOELECTRONICS, MICRO- AND NANOSYSTEM TECHNOLOGIES,
2009,
: 21
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