Rhodium-Catalyzed Regioselective Hydroformylation of Alkynes to α,β-Unsaturated Aldehydes Using Formic Acid

被引：18
|
作者：
Fan, Chao [1 ,2 ]
Hou, Jing [1 ,2 ]
Chen, Yu-Jia [1 ,2 ]
Ding, Kui-Ling [3 ]
Zhou, Qi-Lin [1 ,2 ]
机构：
[1] Nankai Univ, Coll Chem, State Key Lab, Tianjin 300071, Peoples R China
[2] Nankai Univ, Coll Chem, Inst Elemento Organ Chem, Tianjin 300071, Peoples R China
[3] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
ORGANIC LETTERS | 2021年 / 23卷 / 06期
基金：
中国国家自然科学基金;
关键词：
CARBON; HYDROCARBOXYLATION;
D O I：
10.1021/acs.orglett.1c00234
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A rhodium-catalyzed hydroformylation of alkynes with formic acid was developed. The method provides alpha,beta-unsaturated aldehydes in high yield and E-selectivity without the need to handle toxic CO gas.
引用
收藏
页码：2074 / 2077
页数：4
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