Rhodium-catalyzed regioselective olefin hydrophosphorylation

被引：50
|
作者：
Reichwein, JF [1 ]
Patel, MC [1 ]
Pagenkopf, BL [1 ]
机构：
[1] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA
来源：
ORGANIC LETTERS | 2001年 / 3卷 / 26期
关键词：
D O I：
10.1021/ol016989r
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] Parameters influencing the selectivity of the (PPh3)(3)RhCl-catalyzed hydrophosphorylation of olefins and enynes are described. The reaction between differentiated dienes was shown to be highly responsive to olefin substitution. The trimethylsilyl group effectively reversed the normal preference for hydrophosphorylation of an alkyne over an alkene.
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收藏
页码：4303 / 4306
页数：4
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