Photo-induced anti-Markovnikov hydroalkylation of unactivated alkenes employing a dual-component initiator

被引：11
|
作者：
Zhang, Yachao [1 ]
Mao, Liang-Liang [2 ]
Hu, Sifan [1 ]
Luan, Yi [1 ]
Cong, Huan [2 ,3 ]
机构：
[1] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
[2] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China
[3] Univ Chinese Acad Sci, Sch Future Technol, Beijing 100190, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2021年 / 32卷 / 02期
基金：
北京市自然科学基金; 中国国家自然科学基金;
关键词：
Photocatalysis; Anti-Markovnikov; Alkene hydroalkylation; Single-electron transfer; Radical;
D O I：
10.1016/j.cclet.2020.06.026
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal-free anti-Markovnikov hydroalkylation of unactivated alkenes with cyanoacetate has been developed, featuring the use of a dual-component initiator containing an organic photocatalyst and a radical precursor. When combined, the two components can undergo visible light-induced single-electron transfer, and serve as a versatile and effective alkyl radical generator. (C) 2020 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：681 / 684
页数：4
相关论文
共 43 条
  • [1] Photo-induced anti-Markovnikov hydroalkylation of unactivated alkenes employing a dual-component initiator
    Yachao Zhang
    Liang-Liang Mao
    Sifan Hu
    Yi Luan
    Huan Cong
    ChineseChemicalLetters, 2021, 32 (02) : 681 - 684
  • [2] Free-radical anti-Markovnikov hydroalkylation of unactivated alkenes with simple alkanes
    Tian, Yunfei
    Ling, Anbo
    Fang, Ren
    Tan, Ren Xiang
    Liu, Zhong-Quan
    GREEN CHEMISTRY, 2018, 20 (15) : 3432 - 3435
  • [3] Photosensitized Anti-Markovnikov Hydroesterification of Unactivated Alkenes
    Sang, Tongzhi
    Zhou, Chenxing
    Li, Jun
    Liu, Xincong
    Yuan, Yong
    Bao, Xiazhen
    Zhao, Xiaolong
    Huo, Congde
    ORGANIC LETTERS, 2023, 25 (23) : 4371 - 4376
  • [4] Directed Cobalt-Catalyzed anti-Markovnikov Hydroalkylation of Unactivated Alkenes Enabled by "Co-H" Catalysis
    Yang, Dandan
    Huang, Hai
    Li, Meng-Hui
    Si, Xiao-Ju
    Zhang, He
    Niu, Jun-Long
    Song, Mao-Ping
    ORGANIC LETTERS, 2020, 22 (11) : 4333 - 4338
  • [5] Anti-Markovnikov Radical Hydro- and Deuteroamidation of Unactivated Alkenes
    Jiang, Heng
    Studer, Armido
    CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (29) : 7105 - 7109
  • [6] Radical alkylation and protonation induced anti-Markovnikov hydroalkylation of unactivated olefins via cobalt catalysis
    Huang, Shanshan
    Chen, Xiaoyang
    Xu, Zhangwenyi
    Zeng, Xiaobao
    Xiong, Biao
    Qiu, Xiaodong
    CHEMICAL COMMUNICATIONS, 2024, 60 (69) : 9258 - 9261
  • [7] Anti-Markovnikov Hydroamination of Unactivated Alkenes with Primary Alkyl Amines
    Miller, David C.
    Ganley, Jacob M.
    Musacchio, Andrew J.
    Sherwood, Trevor C.
    Ewing, William R.
    Knowles, Robert R.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (42) : 16590 - 16594
  • [8] Nickel-Catalyzed anti-Markovnikov Hydrodifluoroalkylation of Unactivated Alkenes
    Yin, Li-Ming
    Sun, Meng-Chan
    Si, Xiao-Ju
    Yang, Dandan
    Song, Mao-Ping
    Niu, Jun-Long
    ORGANIC LETTERS, 2022, 24 (04) : 1083 - 1087
  • [9] Iodine（Ⅲ） reagent（ABX–N）-induced intermolecular anti-Markovnikov hydroazidation of unactivated alkenes
    Xiaonan Li
    Pinhong Chen
    Guosheng Liu
    Science China(Chemistry), 2019, (11) : 1537 - 1541
  • [10] Gold-Catalyzed Anti-Markovnikov Selective Hydrothiolation of Unactivated Alkenes
    Tamai, Taichi
    Fujiwara, Keiko
    Higashimae, Shinya
    Nomoto, Akihiro
    Ogawa, Akiya
    ORGANIC LETTERS, 2016, 18 (09) : 2114 - 2117
12345