Photosensitized Anti-Markovnikov Hydroesterification of Unactivated Alkenes

被引：2

作者：

Sang, Tongzhi ^{[1
]}

Zhou, Chenxing ^{[1
]}

Li, Jun ^{[1
]}

Liu, Xincong ^{[1
]}

Yuan, Yong ^{[1
]}

Bao, Xiazhen ^{[1
]}

Zhao, Xiaolong ^{[1
]}

Huo, Congde ^{[1
]}

机构：

[1] Northwest Normal Univ, Coll Chem & Chem Engn, Gansu Int Sci & Technol Cooperat Base Water Retent, Key Lab Ecoenvironm Related Polymer Mat,Minist Edu, Lanzhou 730070, Gansu, Peoples R China

来源：

ORGANIC LETTERS | 2023年 / 25卷 / 23期

基金：

中国国家自然科学基金;

关键词：

HYDRATION;

D O I：

10.1021/acs.orglett.3c01527

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hydrofunctionalization of alkenes represents a fundamentalstrategyin synthetic organic chemistry. Herein, we describe a visible-light-promotedapproach for the anti-Markovnikov hydrooxygenation of unactivatedalkenes. Our protocol features the utilization of a cost-effective,bench-stable, and easy-to-handle oxime ester as the reagent, enabledby energy-transfer catalysis. This methodology exhibits excellentfunctional group tolerance and mild reaction conditions, renderingit suitable for the hydroesterification of pharmaceutically relevantmolecule-derived alkenes.

引用

页码：4371 / 4376

页数：6

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