Photo-induced anti-Markovnikov hydroalkylation of unactivated alkenes employing a dual-component initiator

被引：11

作者：

Zhang, Yachao ^{[1
]}

Mao, Liang-Liang ^{[2
]}

Hu, Sifan ^{[1
]}

Luan, Yi ^{[1
]}

Cong, Huan ^{[2
,3
]}

机构：

[1] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China

[2] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China

[3] Univ Chinese Acad Sci, Sch Future Technol, Beijing 100190, Peoples R China

来源：

CHINESE CHEMICAL LETTERS | 2021年 / 32卷 / 02期

基金：

北京市自然科学基金; 中国国家自然科学基金;

关键词：

Photocatalysis; Anti-Markovnikov; Alkene hydroalkylation; Single-electron transfer; Radical;

D O I：

10.1016/j.cclet.2020.06.026

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-free anti-Markovnikov hydroalkylation of unactivated alkenes with cyanoacetate has been developed, featuring the use of a dual-component initiator containing an organic photocatalyst and a radical precursor. When combined, the two components can undergo visible light-induced single-electron transfer, and serve as a versatile and effective alkyl radical generator. (C) 2020 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.

引用

页码：681 / 684

页数：4

共 43 条

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