Photo-induced anti-Markovnikov hydroalkylation of unactivated alkenes employing a dual-component initiator

被引：11
|
作者：
Zhang, Yachao [1 ]
Mao, Liang-Liang [2 ]
Hu, Sifan [1 ]
Luan, Yi [1 ]
Cong, Huan [2 ,3 ]
机构：
[1] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
[2] Chinese Acad Sci, Tech Inst Phys & Chem, Key Lab Photochem Convers & Optoelect Mat, Beijing 100190, Peoples R China
[3] Univ Chinese Acad Sci, Sch Future Technol, Beijing 100190, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2021年 / 32卷 / 02期
基金：
北京市自然科学基金; 中国国家自然科学基金;
关键词：
Photocatalysis; Anti-Markovnikov; Alkene hydroalkylation; Single-electron transfer; Radical;
D O I：
10.1016/j.cclet.2020.06.026
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal-free anti-Markovnikov hydroalkylation of unactivated alkenes with cyanoacetate has been developed, featuring the use of a dual-component initiator containing an organic photocatalyst and a radical precursor. When combined, the two components can undergo visible light-induced single-electron transfer, and serve as a versatile and effective alkyl radical generator. (C) 2020 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：681 / 684
页数：4
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