Dynamic Electric Field Alignment of Metal-Organic Framework Microrods

被引：26

作者：

Cheng, Fei ^{[1
]}

Young, Adam J. ^{[1
,2
]}

Bouillard, Jean-Sebastien G. ^{[3
]}

Kemp, Neil T. ^{[3
]}

Guillet-Nicolas, Remy ^{[4
]}

Hall, Connor H. ^{[3
]}

Roberts, David ^{[1
]}

Jaafar, Ayoub H. ^{[3
]}

Adawi, Ali M. ^{[3
]}

Kleitz, Freddy ^{[4
]}

Imhof, Arnout ^{[5
]}

Reithofer, Michael R. ^{[2
]}

Chin, Jia Min ^{[1
,2
]}

机构：

[1] Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, N Humberside, England

[2] Univ Vienna, Fac Chem, Inst Inorgan Chem, A-1090 Vienna, Austria

[3] Univ Hull, Dept Phys & Math, Kingston Upon Hull HU6 7RX, N Humberside, England

[4] Univ Vienna, Fac Chem, Dept Inorgan Chem Funct Mat, A-1090 Vienna, Austria

[5] Univ Utrecht, Debye Inst Nanomat Sci, Soft Condensed Matter & Biophys, NL-3584 CC Utrecht, Netherlands

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2019年 / 141卷 / 33期

关键词：

POLARIZATION; MECHANISM; NU-1000; GROWTH; LAYER; FILMS; WATER; SOFT;

D O I：

10.1021/jacs.9b06320

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alignment of metal-organic framework (MOF) crystals has previously been performed via careful control of oriented MOF growth on substrates, as well as by dynamic magnetic alignment. We show here that bromobenzene-suspended microrod crystals of the MOF NU-1000 can also be dynamically aligned via electric fields, giving rise to rapid electrooptical responses. This method of dynamic MOF alignment opens up new avenues of MOF control which are important for integration of MOFs into switchable electronic devices as well as in other applications such as reconfigurable sensors or optical systems.

引用

页码：12989 / 12993

页数：5

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