Transformation of a Cluster-Based Metal-Organic Framework to a Rod Metal-Organic Framework

被引：19
|
作者：
Won, Somi [1 ]
Jeong, Seok [1 ]
Kim, Dongwook [1 ]
Seong, Junmo [1 ]
Lim, Jaewoong [1 ]
Moon, Dohyun [2 ]
Baek, Seung Bin [1 ]
Lah, Myoung Soo [1 ]
机构：
[1] Ulsan Natl Inst Sci & Technol, Dept Chem, Ulsan 44919, South Korea
[2] Pohang Acceleratory Lab, Pohang 37673, South Korea
来源：
CHEMISTRY OF MATERIALS | 2022年 / 34卷 / 01期
基金：
新加坡国家研究基金会;
关键词：
RETICULAR CHEMISTRY;
D O I：
10.1021/acs.chemmater.1c03406
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A highly stable and rigid rod metal-organic framework (MOF) is obtained by the single-crystal-to-single-crystal transformation of a Zr-6 cluster-based MOF with highly interconnected but geometrically mismatched building blocks. The transformation results in a significant framework contraction, which comes from the formation of infinite chains of carboxylate- and aquo-linked Zr-6 clusters as a one-dimensional rod secondary building unit. The permanently microporous rod MOF is stable in a variety of solvents, including H2O, and even under very harsh conditions, such as strongly acidic and basic aqueous solutions at 100 degrees C.
引用
收藏
页码：273 / 278
页数：6
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