Transformation of a Cluster-Based Metal-Organic Framework to a Rod Metal-Organic Framework

被引：19

作者：

Won, Somi ^{[1
]}

Jeong, Seok ^{[1
]}

Kim, Dongwook ^{[1
]}

Seong, Junmo ^{[1
]}

Lim, Jaewoong ^{[1
]}

Moon, Dohyun ^{[2
]}

Baek, Seung Bin ^{[1
]}

Lah, Myoung Soo ^{[1
]}

机构：

[1] Ulsan Natl Inst Sci & Technol, Dept Chem, Ulsan 44919, South Korea

[2] Pohang Acceleratory Lab, Pohang 37673, South Korea

来源：

CHEMISTRY OF MATERIALS | 2022年 / 34卷 / 01期

基金：

新加坡国家研究基金会;

关键词：

RETICULAR CHEMISTRY;

D O I：

10.1021/acs.chemmater.1c03406

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A highly stable and rigid rod metal-organic framework (MOF) is obtained by the single-crystal-to-single-crystal transformation of a Zr-6 cluster-based MOF with highly interconnected but geometrically mismatched building blocks. The transformation results in a significant framework contraction, which comes from the formation of infinite chains of carboxylate- and aquo-linked Zr-6 clusters as a one-dimensional rod secondary building unit. The permanently microporous rod MOF is stable in a variety of solvents, including H2O, and even under very harsh conditions, such as strongly acidic and basic aqueous solutions at 100 degrees C.

引用

页码：273 / 278

页数：6

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