Transformation of a Cluster-Based Metal-Organic Framework to a Rod Metal-Organic Framework

被引：19

作者：

Won, Somi ^{[1
]}

Jeong, Seok ^{[1
]}

Kim, Dongwook ^{[1
]}

Seong, Junmo ^{[1
]}

Lim, Jaewoong ^{[1
]}

Moon, Dohyun ^{[2
]}

Baek, Seung Bin ^{[1
]}

Lah, Myoung Soo ^{[1
]}

机构：

[1] Ulsan Natl Inst Sci & Technol, Dept Chem, Ulsan 44919, South Korea

[2] Pohang Acceleratory Lab, Pohang 37673, South Korea

来源：

CHEMISTRY OF MATERIALS | 2022年 / 34卷 / 01期

基金：

新加坡国家研究基金会;

关键词：

RETICULAR CHEMISTRY;

D O I：

10.1021/acs.chemmater.1c03406

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A highly stable and rigid rod metal-organic framework (MOF) is obtained by the single-crystal-to-single-crystal transformation of a Zr-6 cluster-based MOF with highly interconnected but geometrically mismatched building blocks. The transformation results in a significant framework contraction, which comes from the formation of infinite chains of carboxylate- and aquo-linked Zr-6 clusters as a one-dimensional rod secondary building unit. The permanently microporous rod MOF is stable in a variety of solvents, including H2O, and even under very harsh conditions, such as strongly acidic and basic aqueous solutions at 100 degrees C.

引用

页码：273 / 278

页数：6

共 50 条

[21] Metal-organic framework composites
Zhu, Qi-Long
Xu, Qiang
[J]. CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) : 5468 - 5512
[22] Metal-Organic Framework Magnets
Thorarinsdottir, Agnes E.
Harris, T. David
[J]. CHEMICAL REVIEWS, 2020, 120 (16) : 8716 - 8789
[23] Metal-Organic Framework Nanocrystals
Barros, Braulio Silva
de Lima Neto, Otavio Jose
de Oliveira Fros, Allana Christina
Kulesza, Joanna
[J]. CHEMISTRYSELECT, 2018, 3 (26): : 7459 - 7471
[24] Unravelling the synthesis of a rare-earth cluster-based metal-organic framework with spn topology
Bicalho, Hudson A.
Saraci, Felix
Velazquez-Garcia, Jose de J.
Titi, Hatem M.
Howarth, Ashlee J.
[J]. CHEMICAL COMMUNICATIONS, 2022, 58 (78) : 10925 - 10928
[25] Observation of oxygen evolution over a {Ni12}-cluster-based metal-organic framework
Zongsu Han
Zheng Yan
Kunyu Wang
Xinchen Kang
Kai Lv
Xiaoping Zhang
Zhen Zhou
Sihai Yang
Wei Shi
Peng Cheng
[J]. Science China Chemistry, 2022, 65 : 1088 - 1093
[26] Observation of oxygen evolution over a {Ni12}-cluster-based metal-organic framework
Zongsu Han
Zheng Yan
Kunyu Wang
Xinchen Kang
Kai Lv
Xiaoping Zhang
Zhen Zhou
Sihai Yang
Wei Shi
Peng Cheng
[J]. Science China Chemistry, 2022, (06) : 1088 - 1093
[27] Metal-Organic Nanosheets Formed via Defect-Mediated Transformation of a Hafnium Metal-Organic Framework
Cliffe, Matthew J.
Castillo-Martinez, Elizabeth
Wu, Yue
Lee, Jeongjae
Forse, Alexander C.
Firth, Francesca C. N.
Moghadam, Peyman Z.
Fairen-Jimenez, David
Gaultois, Michael W.
Hill, Joshua A.
Magdysyuk, Oxana V.
Slater, Ben
Goodwin, Andrew L.
Grey, Clare P.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (15) : 5397 - 5404
[28] Observation of oxygen evolution over a {Ni12}-cluster-based metal-organic framework
Han, Zongsu
Yan, Zheng
Wang, Kunyu
Kang, Xinchen
Lv, Kai
Zhang, Xiaoping
Zhou, Zhen
Yang, Sihai
Shi, Wei
Cheng, Peng
[J]. SCIENCE CHINA-CHEMISTRY, 2022, 65 (06) : 1088 - 1093
[29] The rise of metal-organic framework based micromotors
Bujalance-Fernandez, Javier
Jurado-Sanchez, Beatriz
Escarpa, Alberto
[J]. CHEMICAL COMMUNICATIONS, 2023, 59 (70) : 10464 - 10475
[30] Metal-Organic Framework Based Thermoluminescence Dosimeter
Yang, Qian
Qin, Haoming
Chen, Lixi
Zhang, Shuya
Mei, Sen
Wu, Deli
Yin, Yuchen
Dai, Xing
Shen, Nannan
Tao, Ye
Luan, Ni
Jin, Aiping
Wang, Yanlong
Chai, Zhifang
Sun, Liang
Liu, Hanzhou
Wang, Shuao
[J]. ACS MATERIALS LETTERS, 2023, 5 (06): : 1619 - 1626

← 1 2 3 4 5 →