A Mesoporous Metal-Organic Framework

被引：298

作者：

Klein, Nicole ^{[1
]}

Senkovska, Irena ^{[1
]}

Gedrich, Kristina ^{[1
]}

Stoeck, Ulrich ^{[1
]}

Henschel, Antje ^{[1
]}

Mueller, Uwe ^{[2
]}

Kaskel, Stefan ^{[1
]}

机构：

[1] Tech Univ Dresden, Dept Inorgan Chem, D-01069 Dresden, Germany

[2] Helmholtz Zentrum Berlin, Mat & Energie BESSYMX Grp, D-12489 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 52期

关键词：

adsorption; gas storage; mesoporous materials; metal-organic frameworks; HYDROGEN UPTAKE; SURFACE-AREA; COORDINATION COPOLYMER; METHANE STORAGE; ADSORPTION; DESIGN;

D O I：

10.1002/anie.200904599

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(figure represented) MOF for more gas storage: A new mesoporous metal-organic framework (MOF) with extremely high adsorption capacities for methane, H2, and n-butane is prepared from the reaction of H 3(btb), H2(2,6-ndc), and zinc nitrate (btb = benzene-1,3,5-tribenzoate; 2,6ndc = 2,6-naphthalenedicarboxylate). The main structural motif is a dodecahedron formed from 12 Zn4O6+ clusters, four 2,6-ndc, and eight btb linkers (see picture; green: Zn 4O6+, gray: C, red: O; the red sphere illustrates the pore volume). © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9954 / 9957

页数：4

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