Synthesis and crystal structure analysis of one dimensional supramolecular [Cd (Glu) (Tu)2]n

被引：0
|
作者：
Ke, Y
Li, J [1 ]
Zhang, Y
机构：
[1] Univ Sci & Technol China, Dept Chem Phys, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
来源：
CRYSTAL RESEARCH AND TECHNOLOGY | 2002年 / 37卷 / 05期
关键词：
cadmium; crystal; one-dimensional; structure; supramolecular; X-ray;
D O I：
10.1002/1521-4079(200205)37:5<501::AID-CRAT501>3.0.CO;2-L
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The complex of [Cd (C5H6O4) (CH4N2S)(2)](n) (I) has been synthesized and its X-ray crystal structure determined at room temperature, M = 394.74, monoclinic, space group Pc (No. 7), with lattice parameters a = 7.683(3), b = 11.566, c = 16.00(1) Angstrom, beta = 100.32(4)degrees, and Z = 4. There are two different Cd sites in this complex. Cd (1) coordinates to four oxygen atoms from Glutaric anion and two sulfide atoms from thiourea. Cd (2) coordinates to three oxygen and two sulfide atoms. The Cd atoms are linked by glutaric anion to form one-dimensional chains. The adjacent chains are held together by hydrogen bonds to form a three dimensional network.
引用
收藏
页码：501 / 508
页数：8
相关论文
共 50 条
  • [21] Synthesis and structure of one-dimensional cadmium coordination polymer [Cd(μ-DPIA)2(H2O)]n
    Gao, S
    Huo, LH
    Lu, ZZ
    Zhao, H
    Zhao, JG
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2005, 21 (08) : 1242 - 1244
  • [22] Synthesis, Crystal Structure and Characterization of a One-dimensional Supramolecular Rare Earth Complex of N-(6-(4-Methylpyridinyl))ketoacetamide
    XU Li TANG Kuan-Zhen MA Yu-Fei TANG Yu ② TAN Min-Yu (State Key Laboratory of Applied Organic Chemistry
    Chinese Journal of Structural Chemistry, 2007, (08) : 877 - 882
  • [23] Synthesis, Crystal Structure and Characterization of a One-dimensional Supramolecular Rare Earth Complex of N-(6-(4-Methylpyridinyl))ketoacetamide
    XU Li TANG KuanZhen MA YuFei TANG Yu TAN MinYu State Key Laboratory of Applied Organic Chemistry College of Chemistry and Chemical Engineering Lanzhou University Lanzhou China
    结构化学, 2007, (08) : 877 - 882
  • [24] Synthesis, crystal structure and supramolecular analysis of chlorendic acid derivatives
    Dardeer, Hemat M.
    Mahgoub, Mohamed Y.
    da Silva, Joao Ferreira
    Elboray, Elghareeb E.
    JOURNAL OF MOLECULAR STRUCTURE, 2021, 1228
  • [25] Synthesis, crystal structure and characterization of a one-dimensional supramolecular rare earth complex of N-(6-(4-methylpyridinyl))ketoacetamide
    Li, Xu
    Kuan-Zhen, Tang
    Yu-Fei, Ma
    Yu, Tang
    Min-Yu, Tan
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2007, 26 (08) : 877 - 882
  • [26] Synthesis and crystal structure of a novel three-dimensional supramolecular network containing one-dimensional honeycomb-like channels
    Guo, YQ
    An, HY
    Li, YG
    Wang, EB
    Wang, XL
    Xu, L
    Hu, CW
    INORGANICA CHIMICA ACTA, 2004, 357 (15) : 4582 - 4586
  • [27] Synthesis and crystal structure of one dimensional coordination polymer [Cu(2-pac)2•2H2O]n
    Zhou Chun-Sheng
    Fan Guang
    Chen San-Ping
    Gao Sheng-Li
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2008, 24 (09) : 1527 - 1530
  • [28] Synthesis and crystal structure of a novel coordination polymer of [Cd(SCN)2(POM)2]n
    Feng, XJ
    Yang, JX
    Yu, WT
    Fun, HK
    Wu, JY
    Tian, YP
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2004, 20 (04) : 403 - 406
  • [29] SYNTHESIS AND CRYSTAL STRUCTURE OF A ONE-DIMENSIONAL POLYMERIC CLUSTER[Mo（μ-S）2Ag（μ-S）2·α-MePyH]n
    Ji Guo LI Xin Quan XIN Department of Chemistry
    ChineseChemicalLetters, 1990, (03) : 255 - 256
  • [30] Synthesis, Crystal Structure and Luminescent Property of One-Dimensional Chain Complex [Cd(FA)(pyim)(H2O)]
    Kong Xue-Jun
    Zhu Kun
    Kai Tian-Han
    Liu Guang-Xiang
    Ren Xiao-Ming
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2009, 25 (12) : 2193 - 2196
12345