Synthesis and crystal structure of one dimensional coordination polymer [Cu(2-pac)2•2H2O]n

被引：0
|
作者：
Zhou Chun-Sheng [1 ,2 ]
Fan Guang [1 ]
Chen San-Ping [1 ]
Gao Sheng-Li [1 ]
机构：
[1] NW Univ Xian, Minist Educ, Key Lab Synthet & Nat Funct Mol Chem, Dept Chem, Xian 710069, Peoples R China
[2] Shangluo Colle, Dept Chem, Shanglou 726000, Shaanxi, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2008年 / 24卷 / 09期
关键词：
coordination polymer; crystal structure; 2-pyrazinecarboxylic acid;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A one-dimensional coordination polymer [Cu(2-pac)(2)center dot 2H(2)O](n) (1) (2-pac=2-pyrazinecarboxylic acid) has been synthesized and structurally characterized by single crystal structure determination method. Crystal data: triclinic, space group P1, a=0.5173(5) nm, b=0.7699(1) nm, c=0.9294(1) nm, alpha=74.832(1)degrees, beta=84.234(2)degrees, gamma= 71.288(1)degrees, V=0.338 3(3) nm(3) Z=1, S=1.037, Final R indices (I > 2 sigma(1) R-1=0.0721, wR(2)=0.1678, for all reflections R-1=0.093 0, wR(2) = 0.187 2. In addition, elemental analysis, IR and thermalgravimetric analysis are presented.
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页码：1527 / 1530
页数：4
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