Synthesis and crystal structure of a novel three-dimensional supramolecular network containing one-dimensional honeycomb-like channels

被引：10

作者：

Guo, YQ ^{[1
]}

An, HY ^{[1
]}

Li, YG ^{[1
]}

Wang, EB ^{[1
]}

Wang, XL ^{[1
]}

Xu, L ^{[1
]}

Hu, CW ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2004年 / 357卷 / 15期

基金：

中国国家自然科学基金;

关键词：

supramolecular network; crystal structure; spiral-shaped chain;

D O I：

10.1016/j.ica.2004.07.020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel supramolecular assembly containing honeycomb-like channels [Cu(mal)(bpy)] (.) 3H(2)O (mal = malate, bpy = 2,2'-bipy) has been synthesized and characterized by elemental analyses, IR, EPR, TG, UV-Vis and single crystal X-ray diffraction. Compound 1 is constructed from spiral-shaped chains via O-(HO)-O-... hydrogen bonds and pi-pi stacking interactions. To our knowledge, compound 1 represents the first supramolecular network constructed from the mixed malate and pyridine ligand. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：4582 / 4586

页数：5

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