Supramolecular architectures constructed by strong hydrogen bonds. Crystal structures of novel one-dimensional polycatenane and three-dimensional interpenetrated network

被引：11
|
作者：
Zhu, HF
Fan, J
Okamura, TA
Sun, WY [1 ]
Ueyama, N
机构：
[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Osaka 5600043, Japan
来源：
CHEMISTRY LETTERS | 2002年 / 09期
关键词：
D O I：
10.1246/cl.2002.898
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report novel supramolecular architectures based on flexible benzene-1,3,5-triacetic acid (bta) through strong hydrogen bonds. Partial deprotonated triacid forms a novel one-dimensional (1D) polycatenated chain (NH4)(15)[1,3,5-C6H3(CH2COOH)(15)(CH2COO)(15)] (1). While In the case of compound bta.H2O (2) with non-deprotonated triacid, a three-dimensional (3D) interpenetrated network was self-organized by strong O-H. .O hydrogen bonds. The conformation of flexible triacid is cis, cis, cis in 1 and cis, trans, trans in 2.
引用
收藏
页码：898 / 899
页数：2
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