A low-cost electrochemical thio- and selenocyanation strategy for electron-rich arenes under catalyst- and oxidant-free conditions

被引：59

作者：

Zhang, Xing ^{[1
]}

Wang, Chenguang ^{[1
]}

Jiang, Hong ^{[1
]}

Sun, Linhao ^{[1
]}

机构：

[1] Huazhong Agr Univ, Dept Chem, Coll Sci, Wuhan 430070, Hubei, Peoples R China

来源：

RSC ADVANCES | 2018年 / 8卷 / 39期

基金：

中国国家自然科学基金;

关键词：

REGIOSELECTIVE THIOCYANATION; HETEROAROMATIC-COMPOUNDS; C-3; THIOCYANATION; INDOLES; ANILINES;

D O I：

10.1039/c8ra04407d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A low-cost and efficient thio- and selenocyanation strategy for electron-rich arenes has been developed under constant-current electrolytic conditions in an undivided cell. This strategy is versatile for various (hetero)aromatic compounds such as indole, pyrrole, aniline and anisole under mild conditions without any catalyst or oxidant. Readily available salts NH4SCN and KSeCN are employed respectively as the sole reagent.

引用

页码：22042 / 22045

页数：4

共 15 条

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