Electrochemical radical annulation of 2-alkynyl biaryls with diselenides under catalyst-and chemical oxidant-free conditions

被引:0
|
作者
Jun Jiang
Ke-Li Wang
Xiao Li
Chao Wu
Hong-Tao Ji
Xiang Chen
Wei-Min He
机构
[1] Postdoctoral Mobile Station of Basic Medical Sciences
[2] Hengyang Medical School
[3] University of South China
关键词
D O I
暂无
中图分类号
O621.256.9 [];
学科分类号
070303 ; 081704 ;
摘要
A facile and efficient electrochemical method for sustainable constructing both selanyl phenanthrenes and selanyl polycyclic heteroaromatics(32 examples, 71%-97% yields) through the radical annulation of 2-alkynyl biaryls and 2-heteroaryl-substituted alkynyl benzenes with diselenides at ambient temperature under additive-, chemical oxidant-, catalyst-free and mild conditions was established.
引用
收藏
页码:172 / 175
页数:4
相关论文
共 50 条
  • [1] Electrochemical radical annulation of 2-alkynyl biaryls with diselenides under catalyst- and chemical oxidant-free conditions
    Jiang, Jun
    Wang, Ke-Li
    Li, Xiao
    Wu, Chao
    Ji, Hong-Tao
    Chen, Xiang
    He, Wei-Min
    [J]. CHINESE CHEMICAL LETTERS, 2023, 34 (12)
  • [2] Selectfluor-Mediated Electrophilic Annulation of 2-Alkynyl Biaryls with Diorganyl Diselenides
    Luo, Qing-Xia
    Ji, Hong-Tao
    Lu, Yu-Han
    Wang, Ke-Li
    Ou, Li-Juan
    He, Wei-Min
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2023, 88 (24): : 16790 - 16796
  • [3] Electrochemical synthesis of selenocyanated imidazo[1,5-a]quinolines under metal catalyst-and chemical oxidant-free conditions
    Jinjin Zhang
    Huiqiao Wang
    Yaru Chen
    Haiquan Xie
    Chenghua Ding
    Jiajing Tan
    Kun Xu
    [J]. Chinese Chemical Letters, 2020, 31 (06) : 1576 - 1579
  • [4] Highly Atom-Economic and Efficient Electrochemical Selenylative Annulation of 2-Alkynyl Biaryls
    Mukherjee, Nilanjana
    Chatterjee, Tanmay
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2023, 365 (13) : 2255 - 2263
  • [5] Recyclable iodine-catalyzed radical selenylative annulation of 2-alkynyl biaryls with diselenides in water: a green approach to selanyl polycyclic aromatic hydrocarbons and polycyclic heteroaromatics
    Mukherjee, Nilanjana
    Satyanarayana, Appanapalli N., V
    Singh, Priti
    Dixit, Mudit
    Chatterjee, Tanmay
    [J]. GREEN CHEMISTRY, 2022, 24 (18) : 7029 - 7038
  • [6] The preparation of difluoromethylated indoles via electrochemical oxidation under catalyst- and oxidant-free conditions
    Zhang, Dong
    Chang, Wenqiao
    Li, Yun
    Zhan, Songying
    Pan, Junjie
    Cai, Shunhui
    Li, Na
    Yang, Xiaoqin
    Fang, Zheng
    [J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2023, 21 (21) : 4440 - 4444
  • [7] Electrochemical synthesis of selenocyanated imidazo[1,5-a]quinolines under metal catalyst- and chemical oxidant-free conditions
    Zhang, Jinjin
    Wang, Huiqiao
    Chen, Yaru
    Xie, Haiquan
    Ding, Chenghua
    Tan, Jiajing
    Xu, Kun
    [J]. CHINESE CHEMICAL LETTERS, 2020, 31 (06) : 1576 - 1579
  • [8] An electrochemical method for deborylative seleno/thiocyanation of arylboronic acids under catalyst- and oxidant-free conditions
    He, Dongdong
    Yao, Jiaojiao
    Ma, Boling
    Wei, Jinghao
    Hao, Guangguo
    Tuo, Xun
    Guo, Shengmei
    Fu, Zhengjiang
    Cai, Hu
    [J]. GREEN CHEMISTRY, 2020, 22 (05) : 1559 - 1564
  • [9] Iodine-Catalyzed Methylthiolative Annulation of 2-Alkynyl Biaryls with DMSO: A Metal-Free Approach to 9-Sulfenylphenanthrenes
    Mukherjee, Nilanjana
    Chatterjee, Tanmay
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (11): : 7881 - 7890
  • [10] A Versatile C-H Halogenation Strategy for Indole Derivatives under Electrochemical Catalyst- and Oxidant-Free Conditions
    Sun, Linhao
    Zhang, Xing
    Li, Zilong
    Ma, Jimei
    Zeng, Zhen
    Jiang, Hong
    [J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2018, 2018 (35) : 4949 - 4952