Some 3-D metal complexes of N,N'-bis(indol-2-oxo-3-ylidene)-1,3-diaminopropane

被引：6
|
作者：
Hassaan, AMA
机构：
[1] Chemistry Department, Faculty of Science, Minia University
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1997年 / 27卷 / 06期
关键词：
D O I：
10.1080/00945719708000231
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Metal chelates of the chlorides and acetates of Ni(II), Co(II), Cu(II), Cr(III), Fe(III) and Mn(II) with N,N'-bis(indol-2-oxo-3-ylidene)-1,3-diaminopropane were prepared and characterized by analytical, conductivity, magnetic, H-1 NMR, infrared and electronic spectral data. It was found that the ligand acts as neutral, dinegative ONNO quadridentate, yielding neutral and cationic complexes. Magnetic and spectral data suggest a square-planar structure for the Ni(II) and Co(II) chelates, an octahedral one for the Mn(II), Fe(III) and Cr(III) chelates and a dimeric penta-coordinate structure for the Cu(II) chelate.
引用
收藏
页码：835 / 842
页数：8
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