Some 3-D metal complexes of N,N'-bis(indol-2-oxo-3-ylidene)-1,3-diaminopropane

被引：6
|
作者：
Hassaan, AMA
机构：
[1] Chemistry Department, Faculty of Science, Minia University
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1997年 / 27卷 / 06期
关键词：
D O I：
10.1080/00945719708000231
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Metal chelates of the chlorides and acetates of Ni(II), Co(II), Cu(II), Cr(III), Fe(III) and Mn(II) with N,N'-bis(indol-2-oxo-3-ylidene)-1,3-diaminopropane were prepared and characterized by analytical, conductivity, magnetic, H-1 NMR, infrared and electronic spectral data. It was found that the ligand acts as neutral, dinegative ONNO quadridentate, yielding neutral and cationic complexes. Magnetic and spectral data suggest a square-planar structure for the Ni(II) and Co(II) chelates, an octahedral one for the Mn(II), Fe(III) and Cr(III) chelates and a dimeric penta-coordinate structure for the Cu(II) chelate.
引用
收藏
页码：835 / 842
页数：8
相关论文
共 50 条
  • [1] The synthesis, characterization and antimicrobial activity of N,N′-bis(2-thiophenecarboxamido)-1,3-diaminopropane and N,N′-bis (2-furancarboxamido)-1,3-diaminopropane and their Cu(II), Zn(II), Co(III) complexes
    Hamurcu, Fatma
    Gunduzalp, Ayla Balaban
    Cete, Servet
    Erk, Birguel
    [J]. TRANSITION METAL CHEMISTRY, 2008, 33 (01) : 137 - 141
  • [2] The synthesis, characterization and antimicrobial activity of N,N′-bis(2-thiophenecarboxamido)-1,3-diaminopropane and N,N′-bis (2-furancarboxamido)-1,3-diaminopropane and their Cu(II), Zn(II), Co(III) complexes
    Fatma Hamurcu
    Ayla Balaban Gündüzalp
    Servet Çete
    Birgül Erk
    [J]. Transition Metal Chemistry, 2008, 33 : 137 - 141
  • [3] [N,N′-bis(5-bromosalicylidene)-1,3-diaminopropane]nickel(II) and [N,N′-bis(5-chlorosalicylidene)-1,3-diaminopropane]copper(II)
    Elmali, A
    Zeyrek, CT
    Elerman, Y
    Svoboda, I
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2000, 56 : 1302 - 1304
  • [4] [N,N′-bis(6-methoxysalicylidene)-1,3-diaminopropane]copper(II)
    Habibi, Mohammad Hossein
    Mokhtari, Reza
    Harrington, Ross W.
    Clegg, William
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M1998 - U1890
  • [5] [N,N′-bis(5-bromosalicylidene)-1,3-diaminopropane]copper(II)
    Kabak, M
    Elmali, A
    Kavlakoglu, E
    Elerman, Y
    Durlu, TN
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 : 1650 - 1652
  • [6] [N,N′-bis(6-methoxysalicylidene)-1,3-diaminopropane] nickel(II)
    Habibi, Mohammad Hossein
    Mokhtari, Reza
    Harrington, Ross W.
    Clegg, William
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M2304 - U528
  • [7] Crystal structure of N,N′-Bis-(2,5-dimethoxybenzylidene)-1,3-diaminopropane
    A. D. Khalaji
    K. Fejfarova
    M. Dusek
    [J]. Journal of Structural Chemistry, 2011, 52 : 1131 - 1133
  • [8] Aqua[N,N′-bis(2-oxidophenylmethyleneimino)-1,3-diaminopropane](thiocyanato)iron(III)
    You, ZL
    Zhu, HL
    Liu, WS
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : M794 - M796
  • [9] Crystal structure of N,N′-Bis-(2,5-dimethoxybenzylidene)-1,3-diaminopropane
    Khalaji, A. D.
    Fejfarova, K.
    Dusek, M.
    [J]. JOURNAL OF STRUCTURAL CHEMISTRY, 2011, 52 (06) : 1131 - 1133
  • [10] TETRAGONAL NICKEL(2) COMPLEXES WITH TETRADENTATE LIGANDS N,N'-BIS(2-PYRIDYLMETHYLENE)-1,3-DIAMINOPROPANE AND N,N'-BIS(2-PYRIDYLMETHYLENE)-1,3-DIAMINO-2-PROPANOL
    CAMPBELL, TG
    URBACH, FL
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1969, (SEP): : IN87 - &
12345