[N,N′-bis(5-bromosalicylidene)-1,3-diaminopropane]nickel(II) and [N,N′-bis(5-chlorosalicylidene)-1,3-diaminopropane]copper(II)

被引：34

作者：

Elmali, A ^{[1
]}

Zeyrek, CT

Elerman, Y

Svoboda, I

机构：

[1] Ankara Univ, Fac Sci, Dept Engn Phys, TR-06100 Ankara, Turkey

[2] Tech Univ Darmstadt, Fachbereich Mat Wissensch, D-64287 Darmstadt, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2000年 / 56卷

关键词：

D O I：

10.1107/S0108270100010428

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compounds, {4,4'-dibromo-2,2'-[1,3-propanediylbis(nitrilomethylidyne-N)]diphenolato-O,O'}nickel(II), [Ni(C-17-H14Br2N2O2)], and {4,4'-dichloro-2,2'-[1,3-propanediylbis(nitrilomethylidyne-N)]diphenolato-O,O'}copper(II), [Cu(C-17-H14Cl2N2O2)], lie on crystallographic twofold axes. In both structures, the metal coordination sphere is a tetrahedrally distorted square plane formed by the four-coordinate N2O2 donor set of the Schiff base imine-phenol ligands. In the Ni compound, the Ni-O and Ni-N distances are 1.908 (3) and 1.959 (4) Angstrom, respectively, while in the Cu compound, the Cu-O and Cu-N distances are 1.907 (2) and 1.960 (2) Angstrom, respectively. The two Schiff base moieties, which themselves are nearly planar, are inclined at an angle of 29.26 (7)degrees for the Ni compound and 29.26 (5)degrees for the Cu compound.

引用

页码：1302 / 1304

页数：3

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