A Three-Dimensional Porous Metal-Organic Framework with a Body-Centered Cubic Topology Constructed from 48-Membered Tetraicosanuclear Metallamacrocycle Based on in Situ Ligand Synthesis

被引：9
|
作者：
Lin Hsiu-Mei [1 ]
Chang Tsung-Yuan [1 ]
机构：
[1] Natl Taiwan Ocean Univ, Inst Biosci & Biotechnol, Chilung 20224, Taiwan
来源：
CRYSTAL GROWTH & DESIGN | 2009年 / 9卷 / 07期
关键词：
HUISGEN 1,3-DIPOLAR CYCLOADDITION; CLICK CHEMISTRY APPROACH; COORDINATION POLYMERS; CLUSTER; DESIGN; ICOSANUCLEAR; TETRAZOLES; AZIDES; UNITS;
D O I：
10.1021/cg900078s
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A three-dimensional metal-organic framework [Cd-3(mu(4)-mtta)(3)(N-3)(3)]center dot 2.5H(2)O with [Cd-24(N-3)(24)] tetraicosanuclear metallamacrocycle as secondary building units (SBUs) and helical character is formed by self-assembly and in situ ligand synthesis. Each tetraicosanuclear metallamacrocycle SBU connects to eight neighboring tetraicosanuclear metallamacrocycle SBUs through 5-methyl tetrazolate (mtta) ligands, resulting in a body-centered cubic (bcu) topology. Thermal stability, variable-temperature powder X-ray diffraction, and luminescence spectrum of the compound were also studied.
引用
收藏
页码：2988 / 2990
页数：3
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