The first tritopic bridging ligand 1,3,5-tris-(4-carboxyphenyl)-benzene (H3BTB) functionalized porous polyoxometalate-based metal-organic framework (POMOF): from design, synthesis to electrocatalytic properties

被引：57

作者：

Dong, Bao-Xia ^{[1
]}

Chen, Lu ^{[1
]}

Zhang, Shi-Yang ^{[1
]}

Ge, Jun ^{[1
]}

Song, Liang ^{[1
]}

Tian, Hui ^{[1
]}

Teng, Yun-Lei ^{[1
]}

Liu, Wen-Long ^{[1
]}

机构：

[1] Yangzhou Univ, Coll Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 03期

关键词：

SELECTIVE SORPTION; COMPUTATIONAL EVALUATION; HYPOTHETICAL POLYMORPHS; MODIFIED ELECTRODE; BUILDING-BLOCKS; REDUCTION; BROMATE; BINDING; STABILITY; NANOSCALE;

D O I：

10.1039/c4dt02486a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Replacing the metal ions (or metal clusters) in routine MOFs with size-matched polyoxoanions to construct POM-based MOF materials (POMOF) combining well-defined crystalline structures, high surface area, regular and tunable cavities is the great challenge in the current POM chemistry area. In this work, we report a 2-fold interpenetrated porous POMOF, [TBA](6)[H3PMo12O40](2)[Zn-8(BTB)(2)]center dot(similar to 35H(2)O), which exhibits effective catalytic activity towards bromate reduction, using the methodology of extension for the reduced transition-metal-grafted epsilon-Keggin polyoxoanions with an expanded tripodal bridging ligand of H3BTB. The simultaneous TGA/DSC-MS technique was applied in this work to identify the evolved gases and was proved to be an effective method for analysing the decomposition process.

引用

页码：1435 / 1440

页数：6

共 13 条

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