A novel three-dimensional CdII metal-organic framework based on [Cd6(malonate)6] metallomacrocycles with zeolite SOD (sodalite) topology: poly[ammine-μ3-malonato-cadmium(II)]

被引：0

作者：

Yuan, Shuai ^{[1
]}

Liu, Mei-Jiao ^{[1
]}

Xie, Han-Yi ^{[1
]}

Xu, Meng-Zhen ^{[1
]}

Sun, Di ^{[1
]}

机构：

[1] Shandong Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Colloid & Interface Chem, Jinan 250100, Shandong, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2012年 / 68卷

关键词：

COORDINATION POLYMERS; CRYSTAL-STRUCTURES; COMPLEX; IMIDAZOLATE; SERIES;

D O I：

10.1107/S0108270112003277

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel CdII metalorganic framework, [Cd(C3H2O4)(NH3)](n), was synthesized by liquid diffusion conducted in the presence of ammonia. The CdII atom has seven-coordinate O6N pentagonalbipyramidal geometry. Six CdII centers are joined by six malonate ligands to form an S6-symmetric [Cd-6(malonate)(6)] metallomacrocycle, which is further extended through a side-on chelating malonate ligand to form a three-dimensional network. Topologically, each CdII center is connected to four others to yield an infinite three-periodic four-coordinated SOD (sodalite) network with point symbol {42 center dot 64}. The overall network structure in the crystal is maintained and stabilized by the presence of N-H...O hydrogen bonds.

引用

页码：M57 / M60

页数：4

共 7 条

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