A novel 3D Cd(II) metal-organic framework with an unprecedented (5,6)-connected topology based on isophthalate and 2-(3-pyridyl)imidazo[4,5-f] 1,10-phenanthroline

被引：29
|
作者：
Wang, Xiuli [1 ]
Liu, Guocheng [1 ]
Zhang, Jinxia [1 ]
Chen, Yongqiang [1 ]
Lin, Hongyan [1 ]
Zheng, Wenyan [1 ]
机构：
[1] Bohai Univ, Fac Chem & Chem Engn, Jinzhou 121000, Peoples R China
来源：
DALTON TRANSACTIONS | 2009年 / 36期
基金：
中国国家自然科学基金;
关键词：
COORDINATION POLYMERS; CRYSTAL-STRUCTURES; BUILDING-BLOCKS; MIXED-LIGANDS; NETWORK; ARCHITECTURES; COMPLEXES; CLUSTERS; DESIGN; PHOTOLUMINESCENT;
D O I：
10.1039/b907839h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel three dimensional cadmium metal-organic framework [Cd(3)(1,3-BDC)(3)(PIP)(2)]center dot 8H(2)O (1) with an unprecedented (5,6)-connected topology has been synthesized from the hydrothermal reaction of cadmium(II) nitrate with the mixed ligands isophthalate acid (1,3-H(2)BDC) and 2-(3-pyridyl) imidazo[4,5-f]1,10-phenanthroline (PIP). Its fluorescence property and thermal stability were investigated.
引用
收藏
页码：7347 / 7349
页数：3
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