A chiral porous 3D metal-organic framework with an unprecedented 4-connected network topology

被引：63
|
作者：
Wu, CD [1 ]
Lin, WB [1 ]
机构：
[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA
来源：
CHEMICAL COMMUNICATIONS | 2005年 / 29期
关键词：
D O I：
10.1039/b505916j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel homochiral 3D metal-organic framework [CdL2(H2O)(2)][ClO4](2)center dot 2DMF center dot 3EtOH center dot 5/3H(2)O, 1, (L = (R)- 6,6'-dichloro- 2,2'-diethoxy-1,1'-binaphthyl-4,4'-bipyridine) exhibits an unprecedented 4-connected network topology owing to the cis- configuration of the Cd coordination and possesses permanent porosity as demonstrated by TGA, XRPD, and CO2 adsorption isotherm studies.
引用
收藏
页码：3673 / 3675
页数：3
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