Synthesis, crystal structure and adsorption property of a microporous Cd(II) metal-organic framework based on 1H-imidazo[4,5-f][1,10]phenanthroline

被引：3
|
作者：
Wang, Jun [1 ,2 ]
Huang, Xiao-ling [1 ]
Cai, Song-liang [1 ]
Zheng, Sheng-run [1 ]
Fan, Jun [1 ]
Zhang, Wei-Guang [1 ]
机构：
[1] South China Normal Univ, Sch Chem & Environm, Guangzhou 510006, Guangdong, Peoples R China
[2] Zhongshan Polytech, Zhongshan 528404, Guangdong, Peoples R China
来源：
POLYHEDRON | 2018年 / 152卷
关键词：
Metal organic frameworks; Gas separation; CO2; separation; 1H-imidazo[4,5-f][1,10]phenanthroline; Sieving effect; SELECTIVE CO2 ADSORPTION; SEPARATION; FUNCTIONALIZATION; PHOTOLUMINESCENCE; COMPLEXES; CAPTURE; CHAINS; WATER; UNITS; MOFS;
D O I：
10.1016/j.poly.2018.06.025
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A microporous metal-organic framework (MOF), [Cd(IP)Cl](n) (1, HIP = 1H-imidazo[4,5-f][1,10]phenanthroline), with 1D square channels along the c axis was constructed through the solvothermal method. Because of the polar nitrogen atoms and the pi-electron-rich ligand, activated MOF la presents a strong interaction with CO2, showing selective capture of CO2 from a mixture of CO2/N-2. Additionally, MOF la also shows significant selective capture of CO2 from CO2/CH4 and CO2/C2H4 mixtures due to the sieving effect of the 1D channels. The column breakthrough experiment results further confirmed that microporous MOF 1a could be used as a potential porous material for selective CO2 adsorption. (C) 2018 Elsevier Ltd. All rights reserved.
引用
收藏
页码：17 / 21
页数：5
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