A New Cadmium(II) 2,6-Naphthalene dicarboxylic Acid Three-Dimensional Metal-Organic Frameworks with 6-Connected PCU Topology

被引:1
|
作者
Xie, Si-Cai [1 ]
机构
[1] Panzhihua Univ, Biol & Chem Engn Coll, Panzhihua 617000, Sichuan, Peoples R China
关键词
Cadmium; Metal-organic framework; PCU topology; 2,6-Naphthalene dicarboxylic acid; COORDINATION POLYMERS;
D O I
10.14233/ajchem.2013.13816A
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel three-dimensional (3D)Cd(II)metal-organic frameworkds [Cd(2,6-ntd)3(DMA)4] (1; 2,6-ntd = 2,6-naphthalene dicarboxylic acid, DMA = N,N'-dimethyl acetamide) has been slovthermally synthesized. Single crystal structure analysis reveals that this compound crystallized in a monoclinic space group of C2/c with a = 14.4124(4) angstrom, b = 18.5328(4) angstrom, c = 21.3181(5) angstrom, alpha = 90.00 degrees, beta = 98.811(2)degrees, lambda = 90.00 degrees, V = 5626.9(2) angstrom(3) and Z = 4. From the viewpoint of topology, it can be reduced to a 6-connected PCU topological network.
引用
收藏
页码:3529 / 3530
页数:2
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