A multifunctional three-dimensional uninodal eight-connected metal-organic framework based on pentanuclear cadmium subunits: New topology, fluorescent and NLO properties

被引：29
|
作者：
Cheng, Lin [1 ]
Hu, Huayou [2 ]
Zhang, Liming [1 ]
Gou, Shaohua [1 ]
机构：
[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Jiangsu, Peoples R China
[2] Huaiyin Normal Univ, Jiangsu Key Lab Chem Low Dimens Mat, Sch Chem & Chem Engn, Huaian 223300, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 15卷
基金：
中国国家自然科学基金;
关键词：
Eight-connected; 3(4)4(14)5(10) topology; Multifunctional material; NLO; SELF-CATENATED NETWORK; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; SINGLE-CRYSTAL; MOLECULAR-COMPLEXES; 3D; CLUSTER; CONSTRUCTION; ADSORPTION; HYDROGEN;
D O I：
10.1016/j.inoche.2011.10.024
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new three-dimensional uninodal eight-connected metal-organic framework (MOF) based on pentanuclear cadmium subunits has been synthesized and characterized. To our knowledge, this is the first example of MOFs with the eight-connected 3(4)4(14)5(10) topology. The framework exhibits high thermal stability until 300 degrees C confirmed by thermogravimetric analysis and has a potential application as a multifunctional material with fluorescent and nonlinear optical (NLO) properties. Crown Copyright (C) 2011 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：202 / 207
页数：6
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