Three-dimensional metal-organic framework based on pentanuclear manganese clusters as building blocks

被引：1

作者：

Li, Xin-Xiong ^{[1
,2
]}

Wei, Kun-Yu ^{[1
]}

Zhuang, Ting-Ting ^{[1
]}

Xia, Wei ^{[1
]}

Chen, Jing-Yu ^{[1
]}

Zhang, Rong-Tao ^{[1
]}

Zheng, Shou-Tian ^{[1
,2
]}

机构：

[1] Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2016年 / 69卷 / 11-13期

关键词：

Metal-organic framework; pentanuclear; manganese; cluster; UNITS; MORPHOLOGIES; CRYSTAL; LIGANDS; CAGES;

D O I：

10.1080/00958972.2016.1193167

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A rare 3-D Mn-organic framework, [(CH3)(2)NH2](3)[Mn-5(btc)(4)(Ac)(H2O)(4)]5H(2)O (1), based on pentanuclear manganese clusters as building blocks has been prepared and structurally characterized by EA, IR, TGA, PXRD, and single-crystal X-ray diffraction. Structural analysis indicates the pentanuclear manganese cluster in 1 has a bow-like configuration, which is the first found to act as secondary building unit in the field of metal-organic framework. Gas adsorption measurements reveal that 1 can absorb a considerable amount of N-2 and CO2. [GRAPHICS] .

引用

页码：1792 / 1801

页数：10

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