Three-dimensional metal-organic framework based on pentanuclear manganese clusters as building blocks

被引：1
|
作者：
Li, Xin-Xiong [1 ,2 ]
Wei, Kun-Yu [1 ]
Zhuang, Ting-Ting [1 ]
Xia, Wei [1 ]
Chen, Jing-Yu [1 ]
Zhang, Rong-Tao [1 ]
Zheng, Shou-Tian [1 ,2 ]
机构：
[1] Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou, Peoples R China
[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2016年 / 69卷 / 11-13期
关键词：
Metal-organic framework; pentanuclear; manganese; cluster; UNITS; MORPHOLOGIES; CRYSTAL; LIGANDS; CAGES;
D O I：
10.1080/00958972.2016.1193167
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A rare 3-D Mn-organic framework, [(CH3)(2)NH2](3)[Mn-5(btc)(4)(Ac)(H2O)(4)]5H(2)O (1), based on pentanuclear manganese clusters as building blocks has been prepared and structurally characterized by EA, IR, TGA, PXRD, and single-crystal X-ray diffraction. Structural analysis indicates the pentanuclear manganese cluster in 1 has a bow-like configuration, which is the first found to act as secondary building unit in the field of metal-organic framework. Gas adsorption measurements reveal that 1 can absorb a considerable amount of N-2 and CO2. [GRAPHICS] .
引用
收藏
页码：1792 / 1801
页数：10
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