Synthesis and Description of a Novel Metal-organic Framework Based on Trigonal Prismatic Building Blocks

被引：5
|
作者：
Li, Bing [1 ,2 ]
Zheng, Shou-Tian [1 ]
Yang, Guo-Yu [1 ]
机构：
[1] Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
[2] Zhejiang Forestry Univ, Dept Chem, Linan 311300, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2009年 / 635卷 / 9-10期
关键词：
Coordination polymers; Metal-Organic frameworks; Hydrothermal synthesis; Crystal structure; X-ray diffraction; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURE; COMPLEXES;
D O I：
10.1002/zaac.200801363
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel metal-organic framework based oil trigonal prismatic building blocks has been hydrothermally prepared and structurally characterized. It crystallizes in the cubic space group Pa (3) over bar with Z = 8. The oxo-centered trinuclear complex units are bridged by 1,3-benzenedicarboxylate (1,3-BDC) ligands, forming a new 3D open-framework [Fe3O(H2O)(3)(1,3-BDC)(3)][Cl]center dot 9H(2)O (1). Its magnetic behavior has been quantitively analyzed by the Bleaney-Bowers equation, indicating the presence of antiferromagnetic interactions within the trinuclear Fe-III atoms.
引用
收藏
页码：1345 / 1347
页数：3
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