Catalytic Hydrogenation of a Model Mixture of Anthracene and Phenanthrene

被引:5
|
作者
Aitbekova, D. E. [1 ]
Yun, Ma Feng [2 ]
Meiramov, M. G. [3 ]
Baikenova, G. G. [4 ,5 ]
Kumakov, F. E. [1 ]
Tusipkhan, A. [1 ]
Mukhametzhanova, S. K. [1 ]
Baikenov, M. I. [1 ]
机构
[1] Buketov State Univ, Karaganda 100028, Kazakhstan
[2] Xinjiang Univ, Urumqi 830000, Peoples R China
[3] Inst Organ Synth & Coal Chem, Karaganda 100008, Kazakhstan
[4] Karaganda Econ Univ Kazpotrebsoyuz, Karaganda 100009, Kazakhstan
[5] South Ural State Univ, Chelyabinsk 454080, Russia
关键词
polyaromatic hydrocarbons; anthracene; phenanthrene; catalytic hydrogenation;
D O I
10.3103/S0361521919040025
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The results of a study on the hydrogenation of a mixture of anthracene and phenanthrene in the presence of nanocatalysts (Fe3O4 and beta-FeOOH) and catalytic additives (microspheres obtained from the ash of coals from the Republic of Kazakhstan and nickel and cobalt additives supported on the microspheres) are presented. The efficiency of a wet mixing method for the preparation of nickel and cobalt oxide catalytic additives on the microspheres in the process of the hydrogenation of a mixture of anthracene and phenanthrene was shown. The hydrogenation process of a mixture of polyaromatic hydrocarbons was represented as a combination of hydrogenation and destruction reactions. The individual chemical composition of the hydrogenation products of a mixture of anthracene and phenanthrene was investigated. The activity and selectivity of the catalysts and catalytic additives in the hydrogenation process of a mixture of polyaromatic hydrocarbons were established.
引用
收藏
页码:230 / 238
页数:9
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