Catalytic Hydrogenation of a Model Mixture of Anthracene and Phenanthrene

被引:5
|
作者
Aitbekova, D. E. [1 ]
Yun, Ma Feng [2 ]
Meiramov, M. G. [3 ]
Baikenova, G. G. [4 ,5 ]
Kumakov, F. E. [1 ]
Tusipkhan, A. [1 ]
Mukhametzhanova, S. K. [1 ]
Baikenov, M. I. [1 ]
机构
[1] Buketov State Univ, Karaganda 100028, Kazakhstan
[2] Xinjiang Univ, Urumqi 830000, Peoples R China
[3] Inst Organ Synth & Coal Chem, Karaganda 100008, Kazakhstan
[4] Karaganda Econ Univ Kazpotrebsoyuz, Karaganda 100009, Kazakhstan
[5] South Ural State Univ, Chelyabinsk 454080, Russia
关键词
polyaromatic hydrocarbons; anthracene; phenanthrene; catalytic hydrogenation;
D O I
10.3103/S0361521919040025
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The results of a study on the hydrogenation of a mixture of anthracene and phenanthrene in the presence of nanocatalysts (Fe3O4 and beta-FeOOH) and catalytic additives (microspheres obtained from the ash of coals from the Republic of Kazakhstan and nickel and cobalt additives supported on the microspheres) are presented. The efficiency of a wet mixing method for the preparation of nickel and cobalt oxide catalytic additives on the microspheres in the process of the hydrogenation of a mixture of anthracene and phenanthrene was shown. The hydrogenation process of a mixture of polyaromatic hydrocarbons was represented as a combination of hydrogenation and destruction reactions. The individual chemical composition of the hydrogenation products of a mixture of anthracene and phenanthrene was investigated. The activity and selectivity of the catalysts and catalytic additives in the hydrogenation process of a mixture of polyaromatic hydrocarbons were established.
引用
收藏
页码:230 / 238
页数:9
相关论文
共 50 条
  • [31] CATALYTIC-HYDROGENATION OF PHENANTHRENE IN CARBON-MONOXIDE WATER-SYSTEM
    BAIKENOV, MI
    KHRUPOV, VA
    MEIRAMOV, MG
    YERMAGAMBETOV, BT
    CHEN, AY
    PIROZHKOV, SD
    LAPIDUS, AL
    PETROLEUM CHEMISTRY, 1992, 32 (03) : 177 - 181
  • [32] Influence of nanocatalytic systems on the hydrogenation of model object - anthracene
    Su, Xintai
    Ma, Fengyun
    Baikenov, M. I.
    Tateeva, A. B.
    Akhmetkarimova, Zh.
    Tusipkhan, A.
    Matayeva, A. Zh.
    Balabekova, D. A.
    Tleubergenova, A. B.
    BULLETIN OF THE UNIVERSITY OF KARAGANDA-CHEMISTRY, 2014, (73): : 50 - 56
  • [33] DELAYED FLUORESCENCE EFFICIENCIES OF ANTHRACENE AND PHENANTHRENE
    LIU, DKK
    FAULKNER, LR
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (09) : 2635 - 2639
  • [34] INFRARED METHOD FOR DETERMINATION OF PHENANTHRENE IN ANTHRACENE
    SZAP, PC
    UTYNOK, WR
    APPLIED SPECTROSCOPY, 1968, 22 (04) : 338 - &
  • [35] CHEMICAL THERMODYNAMIC PROPERTIES OF ANTHRACENE AND PHENANTHRENE
    KUDCHADKER, SA
    KUDCHADKER, AP
    ZWOLINSKI, BJ
    JOURNAL OF CHEMICAL THERMODYNAMICS, 1979, 11 (11): : 1051 - 1059
  • [36] HYDROCRACKING OF ANTHRACENE AND PHENANTHRENE WITH NICKEL CATALYSTS
    RUMOHR, CV
    KOLLING, G
    ERDOL UND KOHLE ERDGAS PETROCHEMIE VEREINIGT MIT BRENNSTOFF-CHEMIE, 1972, 25 (06): : 309 - &
  • [37] REACTION OF CARBETHOXYNITRENE WITH ANTHRACENE PHENANTHRENE AND PYRENE
    BECKWITH, AL
    REDMOND, JW
    AUSTRALIAN JOURNAL OF CHEMISTRY, 1966, 19 (10) : 1859 - &
  • [38] ABNORMAL SUBSTITUTION REACTIONS OF ANTHRACENE AND PHENANTHRENE
    GORE, PH
    JOURNAL OF ORGANIC CHEMISTRY, 1957, 22 (02): : 135 - 138
  • [39] STUDIES ON THE BIOLOGICAL DEGRADATION OF PHENANTHRENE AND ANTHRACENE
    MEGEHEE, MD
    CARRAWAY, AD
    MCGINNIS, GD
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 194 : 128 - AGRO
  • [40] Ionization energies of anthracene, phenanthrene, and naphthacene
    Zakrzewski, VG
    Dolgounitcheva, O
    Ortiz, JV
    JOURNAL OF CHEMICAL PHYSICS, 1996, 105 (19): : 8748 - 8753