Catalytic Hydrogenation of a Model Mixture of Anthracene and Phenanthrene

被引：5

作者：

Aitbekova, D. E. ^{[1
]}

Yun, Ma Feng ^{[2
]}

Meiramov, M. G. ^{[3
]}

Baikenova, G. G. ^{[4
,5
]}

Kumakov, F. E. ^{[1
]}

Tusipkhan, A. ^{[1
]}

Mukhametzhanova, S. K. ^{[1
]}

Baikenov, M. I. ^{[1
]}

机构：

[1] Buketov State Univ, Karaganda 100028, Kazakhstan

[2] Xinjiang Univ, Urumqi 830000, Peoples R China

[3] Inst Organ Synth & Coal Chem, Karaganda 100008, Kazakhstan

[4] Karaganda Econ Univ Kazpotrebsoyuz, Karaganda 100009, Kazakhstan

[5] South Ural State Univ, Chelyabinsk 454080, Russia

来源：

SOLID FUEL CHEMISTRY | 2019年 / 53卷 / 04期

关键词：

polyaromatic hydrocarbons; anthracene; phenanthrene; catalytic hydrogenation;

D O I：

10.3103/S0361521919040025

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The results of a study on the hydrogenation of a mixture of anthracene and phenanthrene in the presence of nanocatalysts (Fe3O4 and beta-FeOOH) and catalytic additives (microspheres obtained from the ash of coals from the Republic of Kazakhstan and nickel and cobalt additives supported on the microspheres) are presented. The efficiency of a wet mixing method for the preparation of nickel and cobalt oxide catalytic additives on the microspheres in the process of the hydrogenation of a mixture of anthracene and phenanthrene was shown. The hydrogenation process of a mixture of polyaromatic hydrocarbons was represented as a combination of hydrogenation and destruction reactions. The individual chemical composition of the hydrogenation products of a mixture of anthracene and phenanthrene was investigated. The activity and selectivity of the catalysts and catalytic additives in the hydrogenation process of a mixture of polyaromatic hydrocarbons were established.

引用

页码：230 / 238

页数：9

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