New prenylated indole alkaloids from fungus Penicillium sp derived of mangrove soil sample

被引：41

作者：

Yang, Bin ^{[1
]}

Dong, Junde ^{[1
]}

Lin, Xiuping ^{[1
]}

Zhou, Xuefeng ^{[1
]}

Zhang, Yanying ^{[1
]}

Liu, Yonghong ^{[1
]}

机构：

[1] Chinese Acad Sci, South China Sea Inst Oceanol, Res Ctr Marine Microbes, Guangdong Key Lab Marine Mat Med,CAS Key Lab Trop, Beijing 100864, Peoples R China

来源：

TETRAHEDRON | 2014年 / 70卷 / 25期

基金：

中国国家自然科学基金;

关键词：

Penicillium sp; Prenylated indole alkaloids; Mangrovamides; X-ray diffraction; Anti-acetylcholinesterase activity; ASPERGILLUS-JAPONICUS; PARAHERQUAMIDE; BIOSYNTHESIS; MALBRANCHEAMIDE; MARCFORTINE; CELLS;

D O I：

10.1016/j.tet.2014.04.043

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Three diprenylated indole alkaloids, mangrovamides A-C (1-3), featured a bicyclo [2.2.2] diazaoctane core and possessed a novel gamma-methyl proline and isoprene derived dimethyl gamma-pyrone functionalities hitherto unknown among the family of paraherquamides, were isolated from the fungus Penicillium sp., which was separated from a mangrove soil sample. The structures were elucidated based on NMR, X-ray, and CD methods. The possible biosynthetic pathway of these compounds is proposed. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：3859 / 3863

页数：5

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